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Fundamental and application of amphiphilic copolymers in high performance MF/UF membranes

Zhu Baoku,Cui Yue,Wang Jun,Wang Nachuan, Yao Zhikan,Zhu Liping

Strategic Study of CAE 2014, Volume 16, Issue 12,   Pages 87-93

Abstract: copolymers and their corresponding blend membrane were presented and investigated.A series of amphiphilic copolymers with different compositions and sequence structures were synthesizedThe synthesized copolymers were blended into various membranes via phase inversion process.It was found that， during the phase inversion process， amphiphilic copolymer migrated spontaneously tocopolymers in real application of the blend membranes.

Keywords： amphiphilic copolymers     blend porous membrane     surface enrichment     hydrophilicity     anti-fouling    

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blending strategy for membrane modification by virtue of surface segregation using surface-tailored amphiphilic

Shuai Liang, Peng Gao, Xiaoqi Gao, Kang Xiao, Xia Huang

Frontiers of Environmental Science & Engineering 2016, Volume 10, Issue 6, doi: 10.1007/s11783-016-0875-5

Abstract: Two types of amphiphilic nanoparticles were prepared via silanization reaction.Amphiphilic nanoparticles tend to protrude from membrane matrix by segregation.Blending with amphiphilic nanoparticles further enhances membrane hydrophilicity.The current study proposed an improved blending modification approach with amphiphilic NPs (aNPs), which

Keywords： Membrane modification     Nanoparticle     Hydrophilic     Amphiphilic     Blending    

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Laser ablation of block copolymers with hydrogen-bonded azobenzene derivatives

Jintang Huang, Youju Huang, Si Wu

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 450-456 doi: 10.1007/s11705-018-1735-6

Abstract:

Supramolecular assemblies (PS-b-P4VP(AzoR)) are fabricated by hydrogen-bonding azobenzene derivatives (AzoR) to poly(4-vinyl pyridine) blocks of polystyrene-block-poly(4-vinyl pyridine) (PS-b-P4VP). PS-b-P4VP(AzoR) forms phase separated nanostructures with a period of ~75–105 nm. A second length scale structure with a period of 2 µm is fabricated on phase separated PS-b-P4VP(AzoR) by laser interference ablation. Both the concentration and the substituent of AzoR in PS-b-P4VP(AzoR) affect the laser ablation process. The laser ablation threshold of PS-b-P4VP(AzoR) decreases as the concentration of AzoR increases. In PS-b-P4VP(AzoR) with different substituents (R= CN, H, and CH3), ablation thresholds follow the trend: PS-b-P4VP(AzoCN)<PS-b-P4VP(AzoCH3)<PS-b-P4VP(AzoH). This result indicates that the electron donor group (CH3) and the electron acceptor group (CN) can lower the ablation threshold of PS-b-P4VP(AzoR).

Keywords： laser ablation     block copolymers     hydrogen-bond     azobenzene derivatives     supramolecular assembly    

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Molecular dynamics study of water diffusion in an amphiphilic block copolymer with large difference in

Yang Zhou, Phillip Choi

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 3,   Pages 440-447 doi: 10.1007/s11705-017-1626-2

Abstract: Isothermal-isobaric molecular dynamics simulation was used to study the diffusion mechanism of water in polyurethane- -poly( -isopropyl acrylamide) (PU- -PNIPAm) with a hydrophobic PU/hydrophilic PNIPAm mass ratio of 1.4 to 1 at 298 K and 450 K. Here, the experimental glass transition temperature ( ) of PU is 243 K while that of PNIPAm is 383 K. Different amounts of water up to 15 wt-% were added to PU- -PNIPAm. We were able to reproduce the specific volumes and glass transition temperatures (250 K and 390 K) of PU- -PNIPAm. The computed self-diffusion coefficient of water increased exponentially with increasing water concentration at both temperatures (i.e., following the free volume model of Fujita). It suggested that water diffusion in PU- -PNIPAm depends only on its fractional free volume despite the free volume inhomogeneity. It is noted that at 298 K, PU is rubbery while PNIPAm is glassy. Regardless of temperature, radial distribution functions showed that water formed clusters with sizes in the range of 0.2–0.4 nm in PU- -PNIPAm. At low water concentrations, more clusters were found in the PU domain but at high water concentrations, more in the PNIPAm domain. It is believed that water molecules diffuse as clusters rather than as individual molecules.

Keywords： molecular dynamics simulation     amphiphilic block copolymer     free volume     water diffusivity     fujita model    

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Surface modification of biomaterials by photochemical immobilization and photograft polymerization to improve hemocompatibility

Yakai FENG, Haiyang ZHAO, Li ZHANG, Jintang GUO,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 3,   Pages 372-381 doi: 10.1007/s11705-010-0005-z

Abstract: The biomimetic amphiphilic phosphorylcholine and Arg-Gly-Asp (RGD) sequence are the most effective and

Keywords： biomimetic amphiphilic     amphiphilic phosphorylcholine     endothelial     functional     biomaterial    

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Synthesis and thermosensitive behavior of dextran graft copolymers containing poly (N-vinylcaprolactam

SHI Huangying, CHEN Wenjuan, ZHANG Liming

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 72-75 doi: 10.1007/s11705-007-0015-7

Abstract: New graft copolymers were synthesized by grafting N-vinylcaprolactam onto dextran.By optical transmittance measurements, it was found that the aqueous solutions of these graft copolymers

Keywords： transmittance     copolymer concentration     LCST     temperature     elemental    

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Erratum to: Multifunctional peptide conjugated amphiphilic cationic copolymer for enhancing ECs targeting

Xinghong Duo, Lingchuang Bai, Jun Wang, Jintang Guo, Xiangkui Ren, Shihai Xia, Wencheng Zhang, Abraham Domb, Yakai Feng

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 1,   Pages 220-220 doi: 10.1007/s11705-020-1995-9

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Visual chiral recognition of 1,1′-binaphthol through enantioselective collapse of gel based on an amphiphilic

Xuhong Zhang, Haimiao Li, Xin Zhang, Meng An, Weiwei Fang, Haitao Yu

Frontiers of Chemical Science and Engineering 2017, Volume 11, Issue 2,   Pages 231-237 doi: 10.1007/s11705-017-1633-3

Abstract: A novel gelator that contained both Schiff base and L-lysine moieties was synthesized and its gelation behavior was tested. This gelator can form gels in various organic solvents. The resulting gel can be applied as a fascinating platform for visual recognition of enantiomeric 1-(2-hydroxynaphthalen-1-yl)naphthalen-2-ol (BINOL) through selective gel collapse. In addition, the mechanism for the reaction of the gel with chiral BINOL was investigated by scanning electron microscope and H nuclear magnetic resonance.

Keywords： gelator     Schiff base     chiral recognition     gel formation     gel collapse    

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Fluorene-based narrow-band-gap copolymers for red light-emitting diodes and bulk heterojunction photovoltaic

SUN Mingliang, WANG Li, XIA Yangjun, DU Bin, LIU Ransheng, CAO Yong

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 3,   Pages 257-264 doi: 10.1007/s11705-008-0052-x

Abstract: A series of narrow band-gap conjugated copolymers (PFO-DDQ) derived from 9,9-dioctylfluorene (DOF) andThe solutions and the thin solid films of the copolymers absorb light from 300–590 nm with two absorbance

Keywords： simulator     Efficient     band-gap     PFO-DDQ50     intensity    

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Synthesis of copolymers of 3-acryloyloxymethyl-3′-methyloxetane and 3-(2-(2-(2-Methoxyethylenoxy)ethylenoxy

YE Lin, ZHAO Yumei, FENG Zengguo, BAI Ying, WU Feng

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 4,   Pages 343-348 doi: 10.1007/s11705-007-0062-0

Abstract: The resulting copolymers were characterized by FTIR, H NMR and Gel Permeation Chromatography (GPC) analyses, and it was found that the enchained ratio of AMO in the copolymers is far lower than its feed ratio

Keywords： 4-butanediol     2-methoxyethylenoxy     consistent     oxetane-derived     copolymer    

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Block copolymers as efficient cathode interlayer materials for organic solar cells

Dingqin Hu, Jiehao Fu, Shanshan Chen, Jun Li, Qianguang Yang, Jie Gao, Hua Tang, Zhipeng Kan, Tainan Duan, Shirong Lu, Kuan Sun, Zeyun Xiao

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 3,   Pages 571-578 doi: 10.1007/s11705-020-2010-1

Abstract: Herein, we design block copolymers with well controlled chemical composition and molecular weight for

Keywords： organic solar cell     block copolymer     cathode interlayer    

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Multifunctional peptide conjugated amphiphilic cationic copolymer for enhancing ECs targeting, penetrating

Xinghong Duo, Lingchuang Bai, Jun Wang, Jintang Guo, Xiangkui Ren, Shihai Xia, Wencheng Zhang, Abraham Domb, Yakai Feng

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 5,   Pages 889-901 doi: 10.1007/s11705-020-1919-8

Abstract: Herein, the multitargeting REDV-G-TAT-G-NLS peptide was conjugated to amphiphilic cationic copolymerethylene glycol)- -hydroxysuccinimide (OPSS-PEG-NHS) linker to prepare PCLMD- -PEI-PEG-REDV-G-TAT-G-NLS copolymersThe multitargeting micelles were prepared from PCLMD- -PEI-PEG-REDV-G-TAT-G-NLS copolymers by self-assembly

Keywords： gene carriers     multitargeting function     ECs     transfection efficiency    

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Preparation of polysulfone-based block copolymer ultrafiltration membranes by selective swelling and sacrificing nanofillers

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 5,   Pages 745-754 doi: 10.1007/s11705-021-2038-x

Abstract: Selective swelling of block copolymers of polysulfone-b-poly(ethylene glycol) is an emerging strategy

Keywords： block copolymers     selective swelling     ultrafiltration     CaCO3 nanoparticles     sacrificial nanofillers    

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Performance and synergistic effect of phenolic and thio antioxidants in ABS graft copolymers

Gongsheng LI, Xuhong GUO, Wang NA, Diancheng HAO, Mingyao ZHANG, Huixuan ZHANG, Jun XU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1,   Pages 26-34 doi: 10.1007/s11705-010-0531-8

Abstract: phenolic and thio antioxidants on the stabilization of acrylonitrile-butadiene-styrene (ABS) graft copolymers

Keywords： antioxidant     ABS graft copolymers     synergistic effect    

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PVDF ultrafiltration membranes of controlled performance via blending PVDF-g-PEGMA copolymer synthesized under different reaction times

Shuai Wang, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

Frontiers of Environmental Science & Engineering 2018, Volume 12, Issue 2, doi: 10.1007/s11783-017-0980-0

Abstract: Polyvinylidene fluoride grafted with poly(ethylene glycol) methyl ether methacrylate (PVDF-g-PEGMA) was synthesized using atomic transfer radical polymerization (ATRP) at different reaction times (9 h, 19 h, and 29 h). The corresponding conversion rates were 10%, 20% and 30%, respectively. PVDF was blended with the copolymer mixture containing PVDF-g-PEGMA, solvent and residual PEGMA under different reaction times. In this study, we explored the effect of the copolymer mixture additives with different synthesis times on cast membrane performance. Increasing the reaction time of PVDF-g-PEGMA causes more PVDF-g-PEGMA and less residual PEGMA to be found in the casting solution. Incremental PVDF-g-PEGMA can dramatically increase the viscosity of the casting solution. An overly high viscosity led to a delayed phase inversion, thus hindering PEGMA segments in PVDF-g-PEGMA from migrating to the membrane surface. However, more residual PEGMA contributed to helping more PEGMA segments migrate to the membrane surface. The pure water fluxes of the blended membrane with reaction times of 9 h, 19 h, and 29 h are 5445 L·m ·h , 1068 L·m ·h and 1179 L·m ·h , respectively, at 0.07 MPa. Delayed phase inversion can form smaller surface pore size distributions, thus decreasing the water flux for the membranes with PVDF-g-PEGMA at 19 h and 29 h. Therefore, we can control the membrane pore size distribution by decreasing the reaction time of PVDF-g-PEGMA to obtain a better flux performance. The membrane with PVDF-g-PEGMA at 19 h exhibits the best foulant rejection and cleaning recovery due to its narrow pore size distribution and high surface oxygen content.

Keywords： Polyvinylidene fluoride ultrafiltration membrane     Amphiphilic copolymer     Blended modification     High flux    

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Title Author Date Type Operation

Fundamental and application of amphiphilic copolymers in high performance MF/UF membranes

Zhu Baoku,Cui Yue,Wang Jun,Wang Nachuan, Yao Zhikan,Zhu Liping

Journal Article

blending strategy for membrane modification by virtue of surface segregation using surface-tailored amphiphilic

Shuai Liang, Peng Gao, Xiaoqi Gao, Kang Xiao, Xia Huang

Journal Article

Laser ablation of block copolymers with hydrogen-bonded azobenzene derivatives

Jintang Huang, Youju Huang, Si Wu

Journal Article

Molecular dynamics study of water diffusion in an amphiphilic block copolymer with large difference in

Yang Zhou, Phillip Choi

Journal Article

Surface modification of biomaterials by photochemical immobilization and photograft polymerization to improve hemocompatibility

Yakai FENG, Haiyang ZHAO, Li ZHANG, Jintang GUO,

Journal Article

Synthesis and thermosensitive behavior of dextran graft copolymers containing poly (N-vinylcaprolactam

SHI Huangying, CHEN Wenjuan, ZHANG Liming

Journal Article

Erratum to: Multifunctional peptide conjugated amphiphilic cationic copolymer for enhancing ECs targeting

Xinghong Duo, Lingchuang Bai, Jun Wang, Jintang Guo, Xiangkui Ren, Shihai Xia, Wencheng Zhang, Abraham Domb, Yakai Feng

Journal Article

Visual chiral recognition of 1,1′-binaphthol through enantioselective collapse of gel based on an amphiphilic

Xuhong Zhang, Haimiao Li, Xin Zhang, Meng An, Weiwei Fang, Haitao Yu

Journal Article

Fluorene-based narrow-band-gap copolymers for red light-emitting diodes and bulk heterojunction photovoltaic

SUN Mingliang, WANG Li, XIA Yangjun, DU Bin, LIU Ransheng, CAO Yong

Journal Article

Synthesis of copolymers of 3-acryloyloxymethyl-3′-methyloxetane and 3-(2-(2-(2-Methoxyethylenoxy)ethylenoxy

YE Lin, ZHAO Yumei, FENG Zengguo, BAI Ying, WU Feng

Journal Article

Block copolymers as efficient cathode interlayer materials for organic solar cells

Dingqin Hu, Jiehao Fu, Shanshan Chen, Jun Li, Qianguang Yang, Jie Gao, Hua Tang, Zhipeng Kan, Tainan Duan, Shirong Lu, Kuan Sun, Zeyun Xiao

Journal Article

Multifunctional peptide conjugated amphiphilic cationic copolymer for enhancing ECs targeting, penetrating

Xinghong Duo, Lingchuang Bai, Jun Wang, Jintang Guo, Xiangkui Ren, Shihai Xia, Wencheng Zhang, Abraham Domb, Yakai Feng

Journal Article

Preparation of polysulfone-based block copolymer ultrafiltration membranes by selective swelling and sacrificing nanofillers

Journal Article

Performance and synergistic effect of phenolic and thio antioxidants in ABS graft copolymers

Gongsheng LI, Xuhong GUO, Wang NA, Diancheng HAO, Mingyao ZHANG, Huixuan ZHANG, Jun XU

Journal Article

PVDF ultrafiltration membranes of controlled performance via blending PVDF-g-PEGMA copolymer synthesized under different reaction times

Shuai Wang, Tong Li, Chen Chen, Baicang Liu, John C. Crittenden

Journal Article